Abstract:Pomegranates from four origins，including Hetian in Xinjiang，Lintong in Shaanxi，Huili in Sichuan，and Mengzi in Yunnan，were used as raw materials for clear juice fermentation，and the volatile components of pomegranate wines from the four origins were analyzed and identified by headspace solid-phase microextractiongas chromatography-mass spectrometry （HS-SPME-GC-MS） combined with rapid gas-phase electronic nose.The results showed that a total of 74 volatile components were detected in pomegranate wines from the four origins，of which the main aroma substances were alcohols，esters，acids，and terpenes. 47，48，53， and 52 volatile compounds were detected in pomegranate wines from A，B，C，and D regions，with total mass concentrations of（2 867.24±392.44） μg/L，（2 310.93±534.42） μg/L，（2 724.23±697.29） μg/L，and （2 264.75±427.53） μg/L，respectively. The external standard method was used to accurately quantify some of the compounds analyzed by GC-MS，and the odor activity value （OAV） was considered. It was found that five characteristic aroma substances were shared by the wines from the four origins，including phenylethanol，ethyl hexanoate，ethyl caprylate，ethyl caprate，and isoamyl acetate. In addition，the results of the electronic nose and GC-MS tests were basically the same，and both could clearly distinguish the large differences between pomegranate wines from different origins. The principal component analysis showed that the pomegranate wines from the four origins were clearly differentiated，and the discriminant factor analysis showed that there was no overlap between the pomegranate wines from the four origins. Therefore，the use of the electronic nose technique can differentiate pomegranate wines from different origins.