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食品研究与开发:2023,44(10):32-38
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超声处理对κ卡拉胶的影响
(1.天津科技大学食品科学与工程学院,天津 300457;2.山东省滨州市沾化区海洋和渔业发展服务中心,山东 滨州 256800)
Effect of Ultrasonic Treatment on κ-Carrageenan
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投稿时间:2022-06-19    
中文摘要: 为利用超声处理改善κ 卡拉胶的溶解性,采用不同超声时间(0~240 min)对κ 卡拉胶进行处理。研究超声处理对卡拉胶分子量、还原糖含量、溶解性、热稳定性、流变性和凝胶质构性等功能性质的影响,从而总结超声对κ 卡拉胶结构和功能性质的作用机制。研究发现κ 卡拉胶分子量、还原糖含量和溶解性的变化受超声时间影响较大。超声处理可明显降低分子量,超声60 min 后,样品常温水溶性指数可达98.91%。通过检测样品还原糖含量随超声时间的变化规律可以发现,超声作用可以使κ 卡拉胶发生解聚和部分降解从而改善其溶解性。流变和凝胶质构分析表明超声处理可以调节样品的黏弹性。超声处理前κ 卡拉胶是硬而脆的凝胶,具有一定泌水性,而超声处理之后,样品的持水性增强,但是热稳定性有所降低。从电镜扫描结果看超声会改变样品表观形态。随着超声时间的延长,κ 卡拉胶表面褶皱逐渐伸展,表面变得光滑,其显微结构呈片状。综上所述,超声处理是改善包括κ 卡拉胶在内的多糖溶解性的有效方法,可以对κ 卡拉胶的流变性、凝胶性等产生一定调节作用,增强持水性,但也会造成热稳定性降低。
Abstract:The solubility of κ-carrageenan was improved by ultrasonic treatment for different time periods (0-240 min).The effects of ultrasonic treatment on the molecular weight,reducing sugar content,solubility,thermal stability,rheology,and gel texture of carrageenan were studied,on the basis of which the mechanism of ultrasonic treatment on the structure and functional properties of κ-carrageenan was explored.The results showed that the molecular weight,reducing sugar content,and solubility of κ-carrageenan were greatly influenced by ultrasonic time.Ultrasonic treatment can significantly reduce the molecular weight,and the water solubility index of the sample at room temperature can reach 98.91% after 60 min of ultrasonic treatment.The variation in reducing sugar content with ultrasonic time indicated that ultrasonic treatment can depolymerize and partially degrade κcarrageenan,thus improving its solubility.The changes of rheology and gel structure suggested that ultrasound regulated the viscoelastic properties of the carrageenan samples.Before ultrasonic treatment,κ-carrageenan was a hard and brittle gel with certain water secretion.After ultrasonic treatment,the sample showed increased water-holding capacity and decreased thermal stability.The results of scanning electron microscopy suggested that ultrasound changed the apparent morphology of the sample.With the extension of ultrasonic time,the sample showed extended surface folds,smoothing surface,and flaky microstructure.To sum up,ultrasound as an effective method to improve the solubility of polysaccharides including κ-carrageenan can regulate the rheology and gelation,enhance the water-holding capacity,and reduce the thermal stability of κ-carrageenan.
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文章编号:202310005     中图分类号:    文献标志码:
基金项目:国家自然科学基金面上项目(32072173)
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