Abstract:The method for analyzing biogenic amines in fermented mash of yellow rice wine （solid-liquid mixture）was established.And the biogenic amine content of fermented mash of yellow rice wine from Shaoxing was determined.The results showed that the detection limits of the eight kinds of biogenic amine were 0.187 μg/L-0.35 μg/L.The limit of quantification was 0.323 μg/L-1.06 μg/L.And the linear relationship was good in the range of 0.5 μg/L-20 μg/L.The average recoveries of the eight kinds of biogenic amine in the yellow rice wine fermented mash samples were 95.31 %-105.22 %，and the relative standard deviations were 3.21 %-9.87%，all of which were less than 10 %.All of the parameters meet the requirements of residue detection in national standards.In the yellow rice wine fermented mash samples，the range of total biogenic amines were 151.02 mg/L-181.48 mg/L.Among the 8 kinds of biogenic amines detected，putrescine and tyramine were the main biogenic amines.