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花生及其制品二氧化硫污染溯源与复合生物酶脱硫工艺优化研究
陈集元
(福建省产品质量检验研究院)
Research on the Traceability of Sulfur Dioxide Pollution in Peanuts and Their Products and Optimization of Composite Enzyme Desulfurization Process
陈集元
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投稿时间:2026-04-30    修订日期:2026-07-28
中文摘要: 针对花生及其制品中二氧化硫残留超标问题,本研究通过污染溯源与控制技术研发形成完整解决方案。采集龙岩主产区 120 批次原料、加工半成品及市售成品,采用酸碱滴定法(GB 5009.34第一法)测定二氧化硫含量,结合生产工艺审计识别关键污染节点,发现烘干环节残留量骤增,成品检出二氧化硫且不符合国家标准。研发复合生物酶协同降解技术,通过响应面法优化得到最优工艺条件:反应温度40.2℃、复合酶活力添加量48.6 U/g、反应时间1.1 h、料液比1:11.3 g/mL。结果显示,该工艺脱硫率达92.5%,可将二氧化硫残留量稳定控制在1.1~7.4 mg/kg,低于国标限量≤10 mg/kg,且对花生品质无显著影响(p>0.05),脆度保持率97.1%、蛋白质损失率仅2.1%。研究证实,熏蒸工艺(占比72.4%)及燃煤供热系统(占比22.9%)是核心污染源,所构建的 “生物酶降解技术+热源燃料改造(燃煤→生物质燃料)” 方案,可有效阻断污染途径,为龙岩花生安全生产提供技术支撑。
Abstract:In response to the issue of excessive sulfur dioxide residue in peanuts and their products, this study has developed a complete solution through pollution tracing and control technology. Collecting 120 batches of raw materials, processed semi-finished products, and commercially available products from the main production area of Longyan, the sulfur dioxide content was determined using acid-base titration method (GB 5009.34 first method). Combined with production process audit to identify key pollution nodes, it was found that the residual amount in the drying process increased sharply, and sulfur dioxide was detected in the finished products, which did not meet national standards. Develop a composite enzyme synergistic degradation technology and optimize the optimal process conditions through response surface methodology: reaction temperature of 40.2 ℃, composite enzyme activity addition of 48.6 U/g, reaction time of 1.1 h, and solid-liquid ratio of 1:11.3 g/mL. The results showed that the desulfurization rate of this process reached 92.5%, and the residual sulfur dioxide could be stably controlled at 1.1-7.4 mg/kg, which was lower than the national standard limit of ≤ 10 mg/kg, and had no significant effect on peanut quality (p>0.05). The brittleness retention rate was 97.1%, and the protein loss rate was only 2.1%. Research has confirmed that fumigation processes (accounting for 72.4%) and coal-fired heating systems (accounting for 22.9%) are the core sources of pollution. The "biological enzyme degradation technology+heat source fuel transformation (coal to biomass fuel)" scheme constructed can effectively block pollution pathways and provide technical support for the safe production of Longyan peanuts.
文章编号:QY20260406     中图分类号:    文献标志码:
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陈集元* 福建省产品质量检验研究院 350002
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陈集元  350002
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