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食品研究与开发:2024,45(13):166-171
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基于紫外-可见和近红外光谱技术的葡萄酒产地鉴别
(河北农业大学食品科技学院,河北保定 071000)
Wine Origin Identification Based on Ultraviolet-Visible and Near-Infrared Spectroscopy
(College of Food Science and Technology,Hebei Agricultural University,Baoding 071000,Hebei,China)
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投稿时间:2023-07-03    
中文摘要: 该研究将紫外-可见光谱、近红外光谱技术与化学计量学方法相结合,建立一种快速、准确鉴别干红葡萄酒产地的方法。采集3 个不同产地(怀涿盆地、宁夏贺兰山东麓和渤海湾)的108 个赤霞珠干红葡萄酒样品的紫外-可见和近红外光谱信息。首先,对比采用标准正态变量变换(standard normal variable,SNV)、一阶导数(first derivative,FD)、二阶导数(second derivative,SD)及不同方法组合对两种光谱数据进行预处理,分别建立随机森林(random forest,RF)、K-最邻近法(K-nearest neighbor,KNN)和最小二乘支持向量机(least squares support vector machine,LS-SVM)判别模型,通过比较建模结果得到最优的预处理-建模方法组合;然后,基于最优判别模型,采用竞争性自适应重加权采样(competitive adaptive reweighted sampling,CARS)算法和无信息变量消除(uninformative variable elimination,UVE)法对光谱数据进行特征波段提取并建立判别模型。结果表明,基于紫外-可见光谱建立的SNV+FD-UVE-LSSVM 模型的校正集和验证集的识别率分别达到97.53%和96.30%,基于近红外光谱建立的FD-CARS-KNN 模型的校正集和验证集的识别率分别达到98.76%和96.30%。该结果证实将紫外-可见光谱、近红外光谱技术与机器学习相结合,有望成为一种简单、快速和低成本的工具,用于鉴别中国干红葡萄酒的地理来源。
Abstract:The quality attributes of wine are closely related to its origin. In recent years,the issue of origin fraud has seriously disrupted the wine market.Therefore,it is necessary to establish a fast,accurate,and realtime method for identifying wine origins. In this study,ultraviolet-visible(UV-Vis)spectroscopy,near-infrared(NIR)spectroscopy,and chemometrics were combined to establish a rapid and accurate identification method for red wine origin. The spectroscopic information of 108 Cabernet Sauvignon red wine samples from three different regions,Huaizhuo Basin,eastern foothills of Helan Mountain in Ningxia,and Bohai Bay,was collected by UV-Vis spectrophotometer and micro-NIR spectrometer. Firstly,standard normal variable(SNV),first derivative(FD),second derivative(SD),and different methods were utilized to preprocess two kinds of spectral data. The discrimination models of random forest(RF),K-nearest neighbor(KNN),and least squares support vector machine(LS-SVM)were built. Comparing the classification effect of the models,the combination of optimal preprocessing and modeling methods was achieved. Secondly,based on the obtained optimal discrimination model,the competitive adaptive reweighted sampling(CARS)and uninformative variable elimination(UVE)were adopted to extract the feature bands of spectral data and build discrimination models. The results showed that the recognition rates of the correction set and the verification set of the SNV-FD-UVE-LSSVM model based on UV-Vis spectrum were 97.53% and 96.30%,respectively,and those of the FD-CARS-KNN model based on NIR spectra were 98.76% and 96.30%.The study showed that combining UV-Vis spectroscopy and NIR spectroscopy with machine learning had the potential to be a simple,fast,and low-cost tool for identifying the geographical origin of Chinese red wine.
文章编号:202413023     中图分类号:    文献标志码:
基金项目:优质葡萄酒酿造及真实性快速精准鉴别关键技术研究(2021C-09)
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