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食品研究与开发:2019,40(7):1-6
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分子量、脱乙酰度与浓度对壳聚糖流变性影响
(上海交通大学农业与生物学院,上海200240)
Effect of Molecular Weight,Degree of Deacetylation and Concentration on Rheological Properties of Chitosan
(School of Agriculture and Biology,Shanghai Jiao Tong University,Shanghai 200240,China)
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投稿时间:2018-09-07    
中文摘要: 壳聚糖在食品工业中常作为被膜剂使用,其流变性能是被膜过程的关键因素。该研究对不同分子量、脱乙酰度和浓度的壳聚糖溶液流变行为在0~300 s-1剪切速率下进行考察,结果表明壳聚糖溶液的流变曲线呈闭合型滞后回路,滞后面积小,回复性强。壳聚糖黏度随分子量与浓度的提高及脱乙酰度的下降呈现上升趋势。在较低分子量和浓度下,壳聚糖溶液呈现剪切变稠特性,提高浓度与分子量会促使溶液从胀塑性流体向假塑性流体的转变。
Abstract:Chitosan is widely used as a coating agent in food industry,and its rheological properties are a key factor in the coating process.The rheological behaviors with shear rates of 0-300 s-1of chitosan film-forming solution with different molecular weights,degree of deacetylation and concentration were considered.The results showed that chitosan solution exhibited closed hysteresis loops with a small lagging area indicating a strong recovery capacity.The viscosity of chitosan increased with the increase of molecular weight and concentration and the decrease of degree of deacetylation.At lower molecular weight and concentration,the chitosan film-forming solution exhibited shear thickening characteristics.Increasing the concentration and molecular weight would promote the transition of the film-forming solution from the dilatant fluid to pseudoplastic fluid.
文章编号:201907001     中图分类号:    文献标志码:
基金项目:国家自然科学基金项目(31501533)
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