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投稿时间:2018-07-09
投稿时间:2018-07-09
中文摘要: 分别以2种不同酒曲发酵的木薯酒为研究对象,采用顶空-固相微萃取技术提取酒中香气成分,并利用气相色谱-质谱联用技术对其香气成分进行分析检测,并对比分析2种酒曲发酵生产的木薯酒的香气成分共同点及差别。结果表明:甜酒曲、白酒曲发酵的木薯酒中分别鉴定出54、31种香气成分,包括醇类、酯类、酸类、醛酮类、芳香类、烷烃类、胺类和醚类等。两种木薯酒中相同的香气成分有12种,其中含量最高的5种香气成分依次为:乙醇、异戊醇、β-苯乙醇和丁二酸二乙酯。对应的相对含量依次为:甜酒曲42.58%、15.08%、15.08%、3.19%,白酒曲70.41%、11.57%、10.55%、0.21%。不同酒曲发酵的木薯酒都含有各自特有的香气成分。乙酸戊酯、2-甲基乙酸丁酯和2,6-二甲基-4-庚醇仅在木薯甜酒中检测到,而乙酸苯乙酯、壬酸乙酯为木薯白酒所特有的挥发性成分。白酒曲产醇能力较强,而甜酒曲产酯、产醛酮及产芳香类能力均为较高水平,这说明两种酒曲发酵功能差距较大。
Abstract:Cassava wine fermented by two different varieties of koji respectively were investigated.The aroma components of wine were detected by headspace solid-phase microextraction,and were analyzed by gas chromatography-mass spectrometry.The commonalities and differences between aroma components of cassava wine fermented by two kinds of distiller's koji were anlalyzed comparatively.The results showed that a total of 54 aroma components were identified in cassava wine fermented with sweet wine koji,and 31 aroma components were identified in cassava wine fermented with spirits koji including alcohols,esters,acids,aldehydes and ketones,aromatic,alkanes,amines and ethers.There were 12 same aroma components in the two kinds of cassava wine,of which the five highest aroma components were ethanol,isoamyl alcohol,β-phenethyl alcohol and diethyl succinate.The corresponding relative contents were:42.58%,15.08%,15.08%,3.19%in sweet wine koji,70.41%,11.57%,10.55%,0.21%in spirits koji.Cassava wine fermented with different koji had their own unique aroma components.Pentyl acetate,acetic acid 2-methylbutyl ester and 2,6-dimethyl-4-heptanol were detected only in cassava sweet wine,while phenylethyl acetate and ethyl nonanoate were the novel volatile components in cassava spirit.The ability of spirits koji to produce alcohol was strong,while sweet wine koji produced high yield of ester,aldehyde,ketone and aromatic compounds,which indicated that there was a big gap between the fermentation functions of two kinds of koji.
keywords: koji cassava wine headspace solid-phase microextraction aroma components gas chromatograph mass spectrometry
文章编号:201902024 中图分类号: 文献标志码:
基金项目:浙江省自然科学基金一般项目(LY18C200006)
作者 | 单位 |
张婷,陈小伟,张沙沙,范昊安,薛淑龙,蒋立新,赵万钙,姚刚,蔡海莺,毛建卫 | 1.浙江科技学院生物与化学工程学院,浙江杭州310023;2.浙江省农产品化学与生物加工技术重点实验室,浙江杭州310023;3.浙江省农业生物资源生化制造协同创新中心,浙江杭州310023 |
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